WebFeb 20, 2009 · The first is the interaction of phenols with hydrophobic sites of zeolite. The second is phenolate complexation with the hydrophilic sites of zeolite (metal ions: Al, Fe, Ti, Na, K, Ca, Mg). (7) Q = Q m 1 K 1 C phenol 1 + K 1 C phenol + Q m 2 K 2 C phenolate 1 + K 2 C phenolate where Q is the amount of phenol adsorbed (mmol Phenols are more acidic than typical alcohols. The acidity of the hydroxyl group in phenols is commonly intermediate between that of aliphatic alcohols and carboxylic acids (their pKa is usually between 10 and 12). Deprotonation of a phenol forms a corresponding negative phenolate ion or phenoxide ion, and the corresponding salts are called phenolates or phenoxides (aryloxides according …
Phenolate - an overview ScienceDirect Topics
WebJan 23, 2024 · Properties of phenol as an acid With indicators The pH of a typical dilute solution of phenol in water is likely to be around 5 - 6 (depending on its concentration). … WebJul 28, 2024 · Figure 2. Schematic of kinetic models following photo-oxidation from phenolate at the water/air surface (surf) and in aqueous solution (aq). Phenolate, Ph –, is photoexcited, Ph – *, and forms a contact pair [Ph:e –] with a rate coefficient k p. [Ph:e –] can either dissociate to the phenoxyl radical, Ph, and e –, with a rate coefficient k d or … エクセル 1 なら a2 なら b
Phenols - Wikipedia
WebMar 2, 2024 · The results of the reaction kinetics, XAS and X-ray structure analyses suggested that the O 2 oxidation from the Ni II-(phenol)(phenolate) complex to the Ni II-phenoxyl radical complex occurs via the proton transfer–electron transfer (PT–ET) type mechanism of the phenol moiety weakly coordinated to the nickel ion. WebAqueous sodium phenolate, made by treating phenol (48.5 g, 0.516 mol) with sodium hydroxide (20.6 g, 0.516 mol) in water (300 ml), was added to ethanol-free chloroform (75 … WebApr 1, 2006 · Phenol removal from liquid phase by Amberlite IRA-420 for pH values higher than 8.0 (a combined elimination by both adsorption and ion exchange). Summarizing, the resin Amberlite IRA-420 could be used to eliminate phenol from liquid phase, due to the high removal capacity observed at high pH, which is higher than the capacity shown by known ... エクセル 1ページ 2ページ 印刷